Mild, efficient Friedel-Crafts acylations from carboxylic acids using cyanuric chloride and AlCl3.
نویسندگان
چکیده
A mild method for Friedel-Crafts acylation with aromatic and aliphatic carboxylic acids using cyanuric chloride, pyridine, and AlCl(3) was developed. Both inter- and intramolecular acylations were achieved at room temperature in high yield and in very short reaction times.
منابع مشابه
Intramolecular Friedel–Crafts acylation of acyclic (h-diene)Fe(CO)3 complexes
Intramolecular cyclization of (h-diene)Fe(CO)3 complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (s, h-allyl)Fe(CO)3 complexes, whereas treatment of the acid chloride complexes with Et3N and AlCl3 provides (h-diene)Fe(CO)3 complexes containing a cyclopentanone moiety. © 2000 Elsevier Science S.A. All rights reserved.
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ورودعنوان ژورنال:
- Organic letters
دوره 10 13 شماره
صفحات -
تاریخ انتشار 2008